Chelating properties of the anionic iridium(III) complex [(eta(5)-C(5)Me(5))IrCl{PO(OMe)(2)}(2)](-). Synthesis of bi- and trinuclear derivatives

dc.contributor.authorValderrama, M
dc.contributor.authorCampos, P
dc.date.accessioned2025-01-21T01:34:16Z
dc.date.available2025-01-21T01:34:16Z
dc.date.issued1996
dc.description.abstractThe synthesis and properties of new neutral complexes of the type [(eta(5)S-C(5)Me(5))IrX{PO(OMe)(2)} {P(OH)(OMe)(2)}] (X=Cl, I) and their thallium derivatives. [(eta(5)-C(5)Me(5))IrX{PO(OMe)(2)}Tl-2] are described. The potentially bidentate or terdentate ligand being the anionic complex [(eta(5)-C(5)Me(5)) IrCl{PO(OMe)(2)}(2)](-) has been studied. It reacts with metal ions and with some organometallic fragments to yield trinuclear or binuclear complexes Spectroscopy data for the isolated complexes are discussed.
dc.fuente.origenWOS
dc.identifier.issn0095-8972
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/97536
dc.identifier.wosidWOS:A1996WA19900001
dc.issue.numero2
dc.language.isoen
dc.pagina.final104
dc.pagina.inicio97
dc.revistaJournal of coordination chemistry
dc.rightsacceso restringido
dc.subjectiridium(III)
dc.subjectalkylphosphonates
dc.subjectsynthesis
dc.subjectbinuclear
dc.subjecttrinuclear
dc.subject.ods12 Responsible Consumption and Production
dc.subject.odspa12 Producción y consumo responsable
dc.titleChelating properties of the anionic iridium(III) complex [(eta(5)-C(5)Me(5))IrCl{PO(OMe)(2)}(2)](-). Synthesis of bi- and trinuclear derivatives
dc.typeartículo
dc.volumen39
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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