Chelating properties of the anionic iridium(III) complex [(eta(5)-C(5)Me(5))IrCl{PO(OMe)(2)}(2)](-). Synthesis of bi- and trinuclear derivatives
dc.contributor.author | Valderrama, M | |
dc.contributor.author | Campos, P | |
dc.date.accessioned | 2025-01-21T01:34:16Z | |
dc.date.available | 2025-01-21T01:34:16Z | |
dc.date.issued | 1996 | |
dc.description.abstract | The synthesis and properties of new neutral complexes of the type [(eta(5)S-C(5)Me(5))IrX{PO(OMe)(2)} {P(OH)(OMe)(2)}] (X=Cl, I) and their thallium derivatives. [(eta(5)-C(5)Me(5))IrX{PO(OMe)(2)}Tl-2] are described. The potentially bidentate or terdentate ligand being the anionic complex [(eta(5)-C(5)Me(5)) IrCl{PO(OMe)(2)}(2)](-) has been studied. It reacts with metal ions and with some organometallic fragments to yield trinuclear or binuclear complexes Spectroscopy data for the isolated complexes are discussed. | |
dc.fuente.origen | WOS | |
dc.identifier.issn | 0095-8972 | |
dc.identifier.uri | https://repositorio.uc.cl/handle/11534/97536 | |
dc.identifier.wosid | WOS:A1996WA19900001 | |
dc.issue.numero | 2 | |
dc.language.iso | en | |
dc.pagina.final | 104 | |
dc.pagina.inicio | 97 | |
dc.revista | Journal of coordination chemistry | |
dc.rights | acceso restringido | |
dc.subject | iridium(III) | |
dc.subject | alkylphosphonates | |
dc.subject | synthesis | |
dc.subject | binuclear | |
dc.subject | trinuclear | |
dc.subject.ods | 12 Responsible Consumption and Production | |
dc.subject.odspa | 12 Producción y consumo responsable | |
dc.title | Chelating properties of the anionic iridium(III) complex [(eta(5)-C(5)Me(5))IrCl{PO(OMe)(2)}(2)](-). Synthesis of bi- and trinuclear derivatives | |
dc.type | artículo | |
dc.volumen | 39 | |
sipa.index | WOS | |
sipa.trazabilidad | WOS;2025-01-12 |