Chelating properties of the anionic iridium(III) complex [(eta(5)-C(5)Me(5))IrCl{PO(OMe)(2)}(2)](-). Synthesis of bi- and trinuclear derivatives
No Thumbnail Available
Date
1996
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
The synthesis and properties of new neutral complexes of the type [(eta(5)S-C(5)Me(5))IrX{PO(OMe)(2)} {P(OH)(OMe)(2)}] (X=Cl, I) and their thallium derivatives. [(eta(5)-C(5)Me(5))IrX{PO(OMe)(2)}Tl-2] are described. The potentially bidentate or terdentate ligand being the anionic complex [(eta(5)-C(5)Me(5)) IrCl{PO(OMe)(2)}(2)](-) has been studied. It reacts with metal ions and with some organometallic fragments to yield trinuclear or binuclear complexes Spectroscopy data for the isolated complexes are discussed.
Description
Keywords
iridium(III), alkylphosphonates, synthesis, binuclear, trinuclear