[CP-ASTERISK-IR(P(O)(OME)2)3]-, AN IRIDIUM(III) PHOSPHONATE COMPLEX ACTING AS A CHELATING OXYGEN LIGAND - SYNTHESIS AND COORDINATION CHEMISTRY

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dc.contributor.authorSCOTTI, M
dc.contributor.authorVALDERRAMA, M
dc.contributor.authorCAMPOS, P
dc.contributor.authorKLAUI, W
dc.date.accessioned2025-01-23T19:21:46Z
dc.date.available2025-01-23T19:21:46Z
dc.date.issued1993
dc.description.abstractThe anionic iridium complex [(C5Me5)Ir{P(O)(OMe)2}3]- (L-) has been prepared as sodium salt from the corresponding trimethyl phosphite complex [(C5Me5)Ir{P(OMe)3}3](ClO4)2. L- reacts with metal ions M2+ to give ML2. With [PtMe3]2SO4 - 4H2O in water and with [{RhCl(cod)}2], cod = 1,5-cyclooctadiene, in cyclohexane solution the air-stable heterobimetallic complexes [LPtMe3] and [LRh(cod)] are formed. The rhodium complex [(C5Me5)Rh{P(O)(OMe)2}3]- (L'-) similarly gives [L'PtMe3] and [L'Rh(cod)]. [LRh(cod)] and [L'Rh(cod)] react with CO gas (1 atm.) to yield [LRh(CO)2] and [L'Rh(CO)2]. Partial decarbonylation of these dicarbonyl complexes at room temperature leads to the tetranuclear complexes [L'Rh(mu-CO)3RhL'](Rh-Rh) and [LRh(mu-CO)3RhL](Rh-Rh).
dc.fuente.origenWOS
dc.identifier.issn0020-1693
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/98866
dc.identifier.wosidWOS:A1993LF64600001
dc.issue.numero2
dc.language.isoen
dc.pagina.final145
dc.pagina.inicio141
dc.revistaInorganica chimica acta
dc.rightsacceso restringido
dc.subject.ods12 Responsible Consumption and Production
dc.subject.odspa12 Producción y consumo responsable
dc.title[CP-ASTERISK-IR(P(O)(OME)2)3]-, AN IRIDIUM(III) PHOSPHONATE COMPLEX ACTING AS A CHELATING OXYGEN LIGAND - SYNTHESIS AND COORDINATION CHEMISTRY
dc.typeartículo
dc.volumen207
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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