Zintl Lewis Superacids: Al(Ge<sub>9</sub>L<sub>3</sub>)<sub>3</sub> (L = H, CH<sub>3</sub>, CHO, CN)

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dc.contributor.authorInostroza-Rivera, Ricardo
dc.contributor.authorParida, Rakesh
dc.contributor.authorNambiar, Sachin
dc.contributor.authorGiri, Santanab
dc.date.accessioned2025-01-20T23:51:08Z
dc.date.available2025-01-20T23:51:08Z
dc.date.issued2021
dc.description.abstractIn quest of a Zintl ion-based Lewis superacids, Al(Ge9L3)(3) {L = H, CH3, CHO and CN} compounds have been designed and their properties have been studied within the framework of conceptual density functional theory-based reactivity descriptors. Superacid property has been identified for these complexes as per the fluoride ion affinity (FIA) values. Studies reveal that Al[Ge-9(CN)(3)](3) and Al[Ge-9(CH3)(3)](3) behave like superacids as their FIA exceeds the value of SbF5, which is considered as the strongest Lewis acid. It has been observed that the ligand plays an important role in reactivity as well as in Lewis acidic property.
dc.fuente.origenWOS
dc.identifier.doi10.1021/acs.jpca.1c00671
dc.identifier.eissn1520-5215
dc.identifier.issn1089-5639
dc.identifier.urihttps://doi.org/10.1021/acs.jpca.1c00671
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/94774
dc.identifier.wosidWOS:000639044900004
dc.issue.numero13
dc.language.isoen
dc.pagina.final2758
dc.pagina.inicio2751
dc.revistaJournal of physical chemistry a
dc.rightsacceso restringido
dc.titleZintl Lewis Superacids: Al(Ge<sub>9</sub>L<sub>3</sub>)<sub>3</sub> (L = H, CH<sub>3</sub>, CHO, CN)
dc.typeartículo
dc.volumen125
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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