Lewis Base Adducts of Phosphine-Stabilized Pb(II) Cations: Synthesis and Catalytic Hydroamination of Alkynes

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dc.contributor.authorChandran, Aswin
dc.contributor.authorBaeza, Jose Miguel Leon
dc.contributor.authorTimofeeva, Vladislava
dc.contributor.authorNougue, Raphael
dc.contributor.authorTakahashi, Shintaro
dc.contributor.authorOhno, Ryoma
dc.contributor.authorBaceiredo, Antoine
dc.contributor.authorGuerrero, Rene Segundo Rojas
dc.contributor.authorSyroeshkin, Mikhail
dc.contributor.authorMatsuo, Tsukasa
dc.contributor.authorSaffon-Merceron, Nathalie
dc.contributor.authorKato, Tsuyoshi
dc.date.accessioned2025-01-20T21:01:55Z
dc.date.available2025-01-20T21:01:55Z
dc.date.issued2022
dc.description.abstractPhosphine-stabilized Pb(II) cations, generated by chloride abstraction from chloroplumbylene 1, readily react with Lewis bases (L) such as phosphines and amines to give the corresponding donor-acceptor complexes 3. These complexes 3 react with phenylacetlylene via alkyne insertion into the Pb-L bond to afford the corresponding vinylplumbylenes 4. Of particular interest, the stable complex 4-HNiPr2 (with a secondary amine) can be used as a hydroamination catalyst of phenylacetylene.
dc.fuente.origenWOS
dc.identifier.doi10.1021/acs.inorgchem.2c02727
dc.identifier.eissn1520-510X
dc.identifier.issn0020-1669
dc.identifier.urihttps://doi.org/10.1021/acs.inorgchem.2c02727
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/92978
dc.identifier.wosidWOS:000868142200001
dc.issue.numero40
dc.language.isoen
dc.pagina.final16162
dc.pagina.inicio16156
dc.revistaInorganic chemistry
dc.rightsacceso restringido
dc.titleLewis Base Adducts of Phosphine-Stabilized Pb(II) Cations: Synthesis and Catalytic Hydroamination of Alkynes
dc.typeartículo
dc.volumen61
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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