Cucurbit[7]uril as a Supramolecular Catalyst in Base-Catalyzed Reactions. Experimental and Theoretical Studies on Carbonate and Thiocarbonate Hydrolysis Reactions

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dc.contributor.authorFierro, Angelica
dc.contributor.authorGarcia-Rio, Luis
dc.contributor.authorArancibia-Opazo, Sandra
dc.contributor.authorAlcazar, Jackson J.
dc.contributor.authorSantos, Jose G.
dc.contributor.authorAliaga, Margarita E.
dc.date.accessioned2025-01-20T22:24:14Z
dc.date.available2025-01-20T22:24:14Z
dc.date.issued2021
dc.description.abstractCucurbit[7]uril (CB7) catalyzes the hydrolysis reaction of bis(4-nitrophenyl)carbonate (1) but inhibits that of bis(4-nitrophenyl)thiocarbonate (2). Two relevant CB7 effects are proposed, a base-catalyst mediated by the CB7 portal and an inhibitory role attributed to the lower interaction of the thiocarbonyl group with the solvent in the host cavity, respectively.
dc.fuente.origenWOS
dc.identifier.doi10.1021/acs.joc.0c02728
dc.identifier.eissn1520-6904
dc.identifier.issn0022-3263
dc.identifier.urihttps://doi.org/10.1021/acs.joc.0c02728
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/94716
dc.identifier.wosidWOS:000643595200065
dc.issue.numero2
dc.language.isoen
dc.pagina.final2027
dc.pagina.inicio2023
dc.revistaJournal of organic chemistry
dc.rightsacceso restringido
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa03 Salud y bienestar
dc.titleCucurbit[7]uril as a Supramolecular Catalyst in Base-Catalyzed Reactions. Experimental and Theoretical Studies on Carbonate and Thiocarbonate Hydrolysis Reactions
dc.typeartículo
dc.volumen86
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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