Reactions of dichloromethane with thioanions .3. Preparation and aminolysis of bis(alkoxythiocarbonylthio)methanes

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dc.contributor.authorBenavente, C
dc.contributor.authorDiaz, P
dc.contributor.authorVega, JC
dc.date.accessioned2025-01-21T01:34:15Z
dc.date.available2025-01-21T01:34:15Z
dc.date.issued1996
dc.description.abstractBis(alkoxythiocarbonylthio)methanes are prepared by reaction of sodium O-alkyldithiocarbonates in water with dichloromethane catalyzed by polyethylenolycol 1,500. The aminolysis of these products with monoalkylamines, in 1:7 molar proportion, in the presence of CH2Cl2 and the polymer above, affords 5-alkyl-1,3,5-dithiazinane, and dialkylcarbamothioate, in 1:2 molar proportion.
dc.fuente.origenWOS
dc.identifier.issn0308-664X
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/97535
dc.identifier.wosidWOS:A1996WE57900006
dc.language.isoen
dc.pagina.final56
dc.pagina.inicio49
dc.revistaPhosphorus sulfur and silicon and the related elements
dc.rightsacceso restringido
dc.subjectdichloromethane double substitution
dc.subjectbis(alkoxythiocarbonylthio) methanes
dc.subject5-alkyl-1,3,5-dithiazinanes
dc.subjectpolyethyleneglycol as catalyst
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa03 Salud y bienestar
dc.titleReactions of dichloromethane with thioanions .3. Preparation and aminolysis of bis(alkoxythiocarbonylthio)methanes
dc.typeartículo
dc.volumen116
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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