Tuning the excited states in <i>fac</i>-[Re(X<sub>2</sub>dppz)(CO)<sub>3</sub>(L)]

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dc.contributor.authorLópez, R
dc.contributor.authorLoeb, B
dc.contributor.authorStriplin, D
dc.contributor.authorDevenney, M
dc.contributor.authorOmberg, K
dc.contributor.authorMeyer, TJ
dc.date.accessioned2025-01-21T01:08:01Z
dc.date.available2025-01-21T01:08:01Z
dc.date.issued2004
dc.description.abstractExcited state lifetime measurements - emission, emission lifetime and Resonance Raman - have been conducted on the series fac-[Re(X(2)dppz)(CO)(3)(L)](0,+) (L = Cl-, 4-ethylpyridine (4-Etpy), 4,4'-bipyridine (4,4'-bpy)), with the X(2)dppz substituted dipyrido[3,2-a:2',3'-c] phenazine ligands (X = CH3 and Cl). The results are consistent with closely lying excited states, with pipi* lowest, but MLCT contributing significantly to excited state lifetimes for the neutral complexes. fac-[Re(Cl(2)dppz)(CO)(3)Cl] appears to undergo a crossover from lowest pipi* to lowest MLCT through the glass to fluid transition.
dc.fuente.origenWOS
dc.identifier.issn0717-9324
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/96414
dc.identifier.wosidWOS:000221509600009
dc.issue.numero2
dc.language.isoen
dc.pagina.final155
dc.pagina.inicio149
dc.revistaJournal of the chilean chemical society
dc.rightsacceso restringido
dc.titleTuning the excited states in <i>fac</i>-[Re(X<sub>2</sub>dppz)(CO)<sub>3</sub>(L)]
dc.typeartículo
dc.volumen49
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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