OXIDATION PROTECTION OF MILD-STEEL BY COATINGS MADE WITH ALUMINUM ALKYLS

dc.contributor.authorCABRERA, AL
dc.contributor.authorZEHNER, JE
dc.contributor.authorARMOR, JN
dc.date.accessioned2025-01-23T19:22:33Z
dc.date.available2025-01-23T19:22:33Z
dc.date.issued1991
dc.description.abstractThe deposition of Al on 1010 steel from mixtures of trimethyl (TMA) and triethyl (TEA) aluminum alkyls in argon and hydrogen was studied. Unlike earlier work with SiH4/H2 no aluminum diffusion onto the steel was observed even when the samples were heated to 800-degrees-C. Coatings obtained with TEA at temperatures between 300-400-degrees-C resulted in overlays of elemental Al or Al oxide after exposure to ambient conditions. No deposition was obtained at temperatures higher than 400-degrees-C in a hot-wall reactor due to rapid decomposition of TEA on the walls of the reactor. Deposition with TMA at temperatures between 400-800-degrees-C resulted in overlays of Al carbide. For deposition at temperatures higher than 500-degrees-C, a cold-wall reactor was used. The Al overlay coatings resulting from TMA were dense, homogeneous, and adhered well to the steel. Both kinds of coatings provided oxidation protection to the steel in air at 800-degrees-C. The performance of the coatings produced with TMA was superior to the coatings produced with TEA and similar to the performance of an Alonized steel.
dc.fuente.origenWOS
dc.identifier.issn0030-770X
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/99056
dc.identifier.wosidWOS:A1991GL48600005
dc.issue.numero3-4
dc.language.isoen
dc.pagina.final280
dc.pagina.inicio265
dc.revistaOxidation of metals
dc.rightsacceso restringido
dc.subjectMILD STEEL PROTECTION
dc.subjectALUMINUM ALKYLS
dc.subjectALUMINIZING
dc.subjectOXIDATION
dc.subjectMICROBALANCE
dc.subjectDEPOSITION
dc.titleOXIDATION PROTECTION OF MILD-STEEL BY COATINGS MADE WITH ALUMINUM ALKYLS
dc.typeartículo
dc.volumen36
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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