<SUP>1</SUP>D and <SUP>2</SUP>D Nuclear magnetic resonance of new silver(I) complexes with achiral and chiral bases as ligands: Crystal structure of [Ag{(S)-(6-CH<sub>3</sub>) C<sub>5</sub>H<sub>3</sub>N-CHN-C<sub>*</sub>H(α-CH<sub>3</sub>)C<sub>6</sub>H<sub>5</sub>}(PPh<sub>3</sub>)<sub>2</sub>](O<sub>3</sub>SCF<sub>3</sub>)

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dc.contributor.authorCifuentes, Olga
dc.contributor.authorContreras, Raul
dc.contributor.authorLaguna, Antonio
dc.contributor.authorCrespo, Olga
dc.date.accessioned2025-01-20T23:59:55Z
dc.date.available2025-01-20T23:59:55Z
dc.date.issued2011
dc.description.abstractTreatment of equimolar amounts of substituted aniline or amine with substituted benzaldehyde leads to the corresponding achiral or chiral Schiff bases (L). The reaction of the bases with [Ag(O3SCF3)(PPh3)] leads to the preparation of three or four coordinated cationic complexes, [Ag(k(1)-L)(PPh3)(n)](+) (n = 1 or 2) which have been characterized by IR, D-1 and D-2 NMR spectroscopy. The crystal structure of [Ag{(S)-(6-CH3)C5H3N-CHN-C*H(alpha-CH3)C6H5}(PPh3)(2)](O3SCF3) is reported. (C) 2011 Elsevier B.V. All rights reserved.
dc.fuente.origenWOS
dc.identifier.doi10.1016/j.ica.2011.09.033
dc.identifier.eissn1873-3255
dc.identifier.issn0020-1693
dc.identifier.urihttps://doi.org/10.1016/j.ica.2011.09.033
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/95316
dc.identifier.wosidWOS:000297266200013
dc.issue.numero1
dc.language.isoen
dc.pagina.final89
dc.pagina.inicio81
dc.revistaInorganica chimica acta
dc.rightsacceso restringido
dc.subjectSilver
dc.subjectSchiff bases
dc.subjectNuclear magnetic resonance
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa03 Salud y bienestar
dc.title<SUP>1</SUP>D and <SUP>2</SUP>D Nuclear magnetic resonance of new silver(I) complexes with achiral and chiral bases as ligands: Crystal structure of [Ag{(S)-(6-CH<sub>3</sub>) C<sub>5</sub>H<sub>3</sub>N-CHN-C<sub>*</sub>H(α-CH<sub>3</sub>)C<sub>6</sub>H<sub>5</sub>}(PPh<sub>3</sub>)<sub>2</sub>](O<sub>3</sub>SCF<sub>3</sub>)
dc.typeartículo
dc.volumen379
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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