Optical and mechanical properties of Zr-oxide doped TiO<sub>2</sub>/SiO<sub>2 </sub>anti-reflective coatings for PV glass covers

dc.contributor.authorZambrano-Mera, Dario F.
dc.contributor.authorEspinoza-Gonzalez, Rodrigo
dc.contributor.authorVillarroel, Roberto
dc.contributor.authorRosenkranz, Andreas
dc.contributor.authorCarvajal, Nicolas
dc.contributor.authorPintor-Monroy, Maria I.
dc.contributor.authorMontano-Figueroa, A. Gabriela
dc.contributor.authorArellano-Jimenez, Maria J.
dc.contributor.authorQuevedo-Lopez, Manuel
dc.contributor.authorValenzuela, Paulina
dc.contributor.authorGacitua, William
dc.date.accessioned2025-01-20T21:05:47Z
dc.date.available2025-01-20T21:05:47Z
dc.date.issued2022
dc.description.abstractMulti-layer systems are frequently used as anti-reflective coatings (ARCs) due to their excellent optical properties. However, these systems suffer from erosive degradation (wear), thus urgently seeking alternative ways to improve their mechanical properties while maintaining their optical response. To tackle this problem, we propose to dope multi-layer TiO2/SiO2 coatings with Zr-oxides to enhance their crystalline structure and density/ compactness, as well as to form Si-Zr-O bonds. We explore the effect of Zr-oxide doping on the microstructure as well as the optical and mechanical properties of multi-layer TiO2/SiO2 coatings with the overall aim to synergistically induce enhanced optical and mechanical properties. Therefore, homogeneous 250 nm thick multi-layer TiO2/SiO2 coatings doped with Zr-oxides (different atomic concentrations) were deposited on glass substrates by magnetron sputtering. Based on our analysis, Zr-doping improves the optical and mechanical properties simultaneously. Among all ARCs, the sample annealed at 400 C and doped with 1 at.-% Zr presented an excellent anti reflective behavior and the best mechanical performance. These characteristics point towards an improved mechanical resistance (outstanding durability) and optical efficiency thus rendering them excellent candidates for the protection of glass covers on solar panels.
dc.fuente.origenWOS
dc.identifier.doi10.1016/j.solmat.2022.111784
dc.identifier.eissn1879-3398
dc.identifier.issn0927-0248
dc.identifier.urihttps://doi.org/10.1016/j.solmat.2022.111784
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/93321
dc.identifier.wosidWOS:000809820100004
dc.language.isoen
dc.revistaSolar energy materials and solar cells
dc.rightsacceso restringido
dc.subjectAnti-reflective coatings
dc.subjectPV glass Cover
dc.subjectZr-oxides doping
dc.subjectOptical properties
dc.subjectMechanical properties
dc.subjectNanoindentation
dc.subject.ods06 Clean Water and Sanitation
dc.subject.odspa06 Agua limpia y saneamiento
dc.titleOptical and mechanical properties of Zr-oxide doped TiO<sub>2</sub>/SiO<sub>2 </sub>anti-reflective coatings for PV glass covers
dc.typeartículo
dc.volumen243
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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