PREPARATION AND PROPERTIES OF PALLADIUM(II) AND RHODIUM(I) COMPLEXES CONTAINING BIDENTATE PHOSPHINE SULFIDE AND SELENIDE LIGANDS

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dc.contributor.authorCONTRERAS, R
dc.contributor.authorVALDERRAMA, M
dc.contributor.authorYANEZ, S
dc.date.accessioned2025-01-23T19:21:52Z
dc.date.available2025-01-23T19:21:52Z
dc.date.issued1993
dc.description.abstractThe synthesis and properties of cationic complexes of general formula (ML2{CH2(Ph2PE)2)]BF4, where M = Pd(II) and Rh(II), L2 = eta3-MeC3H4, {P(O)(OR)2}2H (R = Me, Et), COD, (CO)2, (CO)PPh3 and E = S, Se are described. The methylene proton of the coordinated phosphine sulphide or selenide ligands react with strong bases as BuLi in n-hexane or NaH in THF, to give neutral complexes of the type [ML2{CH(Ph2PE)2)], where M = Pd(II), Rh(I); L2 = eta3-MeC3H4, COD and E = S, Se. The complexes have been characterized by elemental analyses, molar conductivities, i.r., H-1 n.m.r. and P-31{H-1} n.m.r. spectroscopy.
dc.fuente.origenWOS
dc.identifier.issn0340-4285
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/98895
dc.identifier.wosidWOS:A1993KM39500018
dc.issue.numero1
dc.language.isoen
dc.pagina.final76
dc.pagina.inicio73
dc.revistaTransition metal chemistry
dc.rightsacceso restringido
dc.subject.ods12 Responsible Consumption and Production
dc.subject.odspa12 Producción y consumo responsable
dc.titlePREPARATION AND PROPERTIES OF PALLADIUM(II) AND RHODIUM(I) COMPLEXES CONTAINING BIDENTATE PHOSPHINE SULFIDE AND SELENIDE LIGANDS
dc.typeartículo
dc.volumen18
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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