Solid-phase selenium-catalyzed selective allylic chlorination of polyprenoids

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dc.contributor.authorBarrero, Alejandro F.
dc.contributor.authorQuilez del Moral, Jose F.
dc.contributor.authorMar Herrador, M.
dc.contributor.authorCortes, Manuel
dc.contributor.authorArteaga, Pilar
dc.contributor.authorCatalan, Julieta V.
dc.contributor.authorSanchez, Elena M.
dc.contributor.authorArteaga, Jesus F.
dc.date.accessioned2025-01-21T01:06:03Z
dc.date.available2025-01-21T01:06:03Z
dc.date.issued2006
dc.description.abstractRegioselective halogenation of the terminal isopropylidene unit of different acyclic polyolefinic polyprenoids (farnesyl acetate, geranylgeranyl acetate, squalene, etc.) using NCS/ catalytic polymer-supported selenenyl bromide is described; good to excellent yields are obtained (68-96%). The first applications of this protocol include the concise synthesis of bioactive terpenoids 1-3.
dc.fuente.origenWOS
dc.identifier.doi10.1021/jo060760d
dc.identifier.issn0022-3263
dc.identifier.urihttps://doi.org/10.1021/jo060760d
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/96076
dc.identifier.wosidWOS:000239017500055
dc.issue.numero15
dc.language.isoen
dc.pagina.final5814
dc.pagina.inicio5811
dc.revistaJournal of organic chemistry
dc.rightsacceso restringido
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa03 Salud y bienestar
dc.titleSolid-phase selenium-catalyzed selective allylic chlorination of polyprenoids
dc.typeartículo
dc.volumen71
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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