SYNTHESIS, SOLUTION PROPERTIES, AND CHAIN FLEXIBILITY OF POLY (METHYL DODECYL ITACONATE)

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dc.contributor.authorLEON, A
dc.contributor.authorLOPEZ, M
dc.contributor.authorGARGALLO, L
dc.contributor.authorRADIC, D
dc.contributor.authorHORTA, A
dc.date.accessioned2024-01-10T12:09:07Z
dc.date.available2024-01-10T12:09:07Z
dc.date.issued1990
dc.description.abstractThe dilute solution behavior of poly(methyl dodecyl itaconate) (PMeDoI) has been studied in THF and n-butanol at 298 K, by intrinsic viscosity, light scattering, and size-exclusion chromatography (SEC) measurements. The Kuhn-Mark-Houwink-Sakurada relationships were established. The flexibility factors sigma and C infinity and the thermodynamic parameters B were calculated using the Stockmayer-Fixman equation. The A2 and the B values are indicative of the presence of the excluded volume effect. The results obtained are compared with those previously found for poly(mono dodecyl itaconate) (PMDoI) and discussed in terms of specific influence of the free carboxylic group in the poly(monoester).
dc.fechaingreso.objetodigital2024-05-06
dc.format.extent9 páginas
dc.fuente.origenWOS
dc.identifier.doi10.1080/00222349008230375
dc.identifier.issn0022-2348
dc.identifier.urihttps://doi.org/10.1080/00222349008230375
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/76460
dc.identifier.wosidWOS:A1990EU97800004
dc.information.autorucQuímica;Gargallo L;S/I;98194
dc.information.autorucQuímica;Radic D;S/I;49367
dc.issue.numero4
dc.language.isoen
dc.nota.accesocontenido parcial
dc.pagina.final359
dc.pagina.inicio351
dc.publisherTAYLOR & FRANCIS INC
dc.revistaJOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS
dc.rightsacceso restringido
dc.subjectVISCOMETRIC BEHAVIOR
dc.subjectDILUTE-SOLUTION
dc.subjectCONFORMATION
dc.subject.ods06 Clean Water and Sanitation
dc.subject.odspa06 Agua limpia y saneamiento
dc.titleSYNTHESIS, SOLUTION PROPERTIES, AND CHAIN FLEXIBILITY OF POLY (METHYL DODECYL ITACONATE)
dc.typeartículo
dc.volumen29
sipa.codpersvinculados98194
sipa.codpersvinculados49367
sipa.indexWOS
sipa.trazabilidadCarga SIPA;09-01-2024
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