Mild and rapid method for the generation of <i>o</i>-quinone methide intermediates.: Synthesis of puupehedione analogues

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dc.contributor.authorBarrero, Alejandro F.
dc.contributor.authordel Moral, Jose F. Quilez
dc.contributor.authorHerrador, M. Mar
dc.contributor.authorArteaga, Pilar
dc.contributor.authorCortes, Manuel
dc.contributor.authorBenites, Julio
dc.contributor.authorRosellon, Antonio
dc.date.accessioned2025-01-21T01:06:06Z
dc.date.available2025-01-21T01:06:06Z
dc.date.issued2006
dc.description.abstractA route to simpler analogues to bioactive puupehedione derivatives involving a hetero Diels-Alder cycloaddition of a o-quinone methide is described. These intermediate species are generated via fluoride-induced desilylation of silyl derivatives of o-hydroxybenzyl iodides. Remarkable short reaction times and very mild experimental conditions are the main features of this method. (c) 2006 Elsevier Ltd. All rights reserved.
dc.fuente.origenWOS
dc.identifier.doi10.1016/j.tet.2006.04.004
dc.identifier.issn0040-4020
dc.identifier.urihttps://doi.org/10.1016/j.tet.2006.04.004
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/96087
dc.identifier.wosidWOS:000238171600021
dc.issue.numero25
dc.language.isoen
dc.pagina.final6017
dc.pagina.inicio6012
dc.revistaTetrahedron
dc.rightsacceso restringido
dc.subjectcyclisation
dc.subjectepoxides
dc.subjecttitanium
dc.subjectradical reaction
dc.subjectterpenoids
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa03 Salud y bienestar
dc.titleMild and rapid method for the generation of <i>o</i>-quinone methide intermediates.: Synthesis of puupehedione analogues
dc.typeartículo
dc.volumen62
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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