CATIONIC HOMOBINUCLEAR AND HETEROBINUCLEAR RUTHENIUM(II)-RHODIUM(III) COMPLEXES WITH DIMETHYL PHOSPHONATE AND HALIDES AS BRIDGING LIGANDS

VALDERRAMA, M; CONTRERAS, R; ACEVEDO, J

CATIONIC HOMOBINUCLEAR AND HETEROBINUCLEAR RUTHENIUM(II)-RHODIUM(III) COMPLEXES WITH DIMETHYL PHOSPHONATE AND HALIDES AS BRIDGING LIGANDS

Date

1995

Authors

VALDERRAMA, M

CONTRERAS, R

ACEVEDO, J

Abstract

The synthesis of new anionic complexes of formula [(ring)MX(2){PO(OMe)(2)}](-) is described; they have been used as tridentate X,X',O-tripod-like ligands for the preparation of bimetallic compounds [{(ring)M}(2)(mu-1)(2){mu-PO(OMe)(2)}](+) and [(eta(6)-MeC(6)H(4)Pr(1))Ru(mu-Cl)(2){mu-PO(OMe)(2)}Rh(eta(5)-C(5)Me(5))](+).