Alkali-Boosted Catalytic Activity of Co-Based Catalysts Supported by Nanoporous Carbon in the Hydrodeoxygenation of Guaiacol

Simple item page
dc.catalogadorjlo
dc.contributor.authorMatos, Juan
dc.contributor.authorSamudio González, Diana
dc.contributor.authorBlanco, Elodie
dc.contributor.authorPoon, Po S.
dc.contributor.authorEscalona Burgos, Néstor Guillermo
dc.date.accessioned2025-03-06T19:32:02Z
dc.date.available2025-03-06T19:32:02Z
dc.date.issued2025
dc.description.abstractThe catalytic activity and selectivity of Co-based catalysts supported on home-made nanoporous carbon was studied as a function of the type of alkali promoter (Ca and Mg). The catalysts were characterized by N2 adsorption/desorption isotherms, temperature-programmed reduction, CO chemisorption, and X-ray diffraction patterns. The catalysts were compared against carbon-supported alkali-promoted Ni-based catalysts and Re-containing catalysts. The catalytic activity of the Co-based catalyst was clearly enhanced in the presence of Ca and Mg, and it was higher than the Ni-based catalysts and comparable to that obtained using an ReC catalyst. The initial activity of the Mg-promoted catalyst increased by a factor of up to 2.5 times higher compared to the non-promoted catalyst. Moreover, this catalyst showed a turnover frequency of up to 5 times higher than equivalent carbon-supported Re-based catalysts. Significant changes were not observed in the selectivity of products after the incorporation of alkali, with cyclohexane being the main product. However, it was demonstrated that the presence of alkali led to a faster and higher production of cyclohexane from the demethoxylation of phenol and the dehydrogenation of cyclohexanol. The present results suggest that Co-based catalysts are an economical alternative for the catalytic conversion of representative target molecules from bio-oil feed.
dc.fechaingreso.objetodigital2025-03-06
dc.format.extent12 páginas
dc.fuente.origenWOS
dc.identifier.doi10.3390/catal15010017
dc.identifier.eissn2073-4344
dc.identifier.issn2073-4344
dc.identifier.urihttps://doi.org/10.3390/catal15010017
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/102413
dc.identifier.wosidWOS:001403686500001
dc.information.autorucEscuela de Ingeniería; Blanco, Elodie; 0000-0001-9955-8394; 1056872
dc.information.autorucEscuela de Química; Escalona Burgos, Néstor Guillermo; 0000-0002-2628-4609; 1021533
dc.issue.numero1
dc.language.isoen
dc.nota.accesocontenido completo
dc.revistaCatalysts
dc.rightsacceso abierto
dc.subjectCo-based catalysts
dc.subjectAlkali promotors
dc.subjectGuaiacol conversion
dc.subjectActivity/selectivity
dc.subjectBiorefinery
dc.subject.ddc510
dc.subject.deweyMatemática física y químicaes_ES
dc.titleAlkali-Boosted Catalytic Activity of Co-Based Catalysts Supported by Nanoporous Carbon in the Hydrodeoxygenation of Guaiacol
dc.typeartículo
dc.volumen15
sipa.codpersvinculados1056872
sipa.codpersvinculados1021533
sipa.trazabilidadWOS;2025-02-01
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
catalysts-15-00017-v2.pdf
Size:
1.41 MB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Artículos de revistas