Synthesis and single-crystal characterization of the square planar complex [Ni{(SPPh<sub>2</sub>)<sub>2</sub> N-S,S′}<sub>2</sub>]•2THF
| dc.contributor.author | Simón-Manso, E | |
| dc.contributor.author | Valderrama, M | |
| dc.contributor.author | Boys, D | |
| dc.date.accessioned | 2025-01-21T01:30:47Z | |
| dc.date.available | 2025-01-21T01:30:47Z | |
| dc.date.issued | 2001 | |
| dc.description.abstract | Reaction of Ni(CO)(4) with HN(SPPh2)(2) in tetrahydrofuran yielded the nickel(II) neutral complex [Ni-{(SPPh2)(2)}(2)N-S,S'].2THF. X-ray crystallography shows a square planar NiS4 core, with a center of inversion at Ni atom. It crystallized in the space group P(1)over-bar. This compound easily isomerizes in organic solvents at room temperature or by heating a solid-state sample to form the corresponding tetrahedral isomer. | |
| dc.description.abstract | <Graphics> | |
| dc.fuente.origen | WOS | |
| dc.identifier.issn | 0020-1669 | |
| dc.identifier.uri | https://repositorio.uc.cl/handle/11534/96892 | |
| dc.identifier.wosid | WOS:000169550700060 | |
| dc.issue.numero | 14 | |
| dc.language.iso | en | |
| dc.pagina.final | 3649 | |
| dc.pagina.inicio | 3647 | |
| dc.revista | Inorganic chemistry | |
| dc.rights | acceso restringido | |
| dc.subject.ods | 03 Good Health and Well-being | |
| dc.subject.odspa | 03 Salud y bienestar | |
| dc.title | Synthesis and single-crystal characterization of the square planar complex [Ni{(SPPh<sub>2</sub>)<sub>2</sub> N-S,S′}<sub>2</sub>]•2THF | |
| dc.type | artículo | |
| dc.volumen | 40 | |
| sipa.index | WOS | |
| sipa.trazabilidad | WOS;2025-01-12 |