THERMAL-DEGRADATION AND DETERMINATION OF KINETIC-PARAMETERS BY DYNAMIC THERMOGRAVIMETRY OF COPOLYMERS SYNTHESIZED WITHOUT INITIATOR

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dc.contributor.authorRIVAS, BL
dc.contributor.authorPIZARRO, GD
dc.contributor.authorCATALAN, RE
dc.contributor.authorTAGLE, LH
dc.date.accessioned2025-01-23T19:22:32Z
dc.date.available2025-01-23T19:22:32Z
dc.date.issued1991
dc.description.abstractThe thermal degradation of a series of 18 copolymers of 2-methylaziridine and 1-(2-hydroxyethyl)aziridine with N-phenylmaleimide and derivatives obtained without added catalyst, was investigated using thermogravimetry (TGA) under a dynamic nitrogen atmosphere over a temperature range from 20 to 500-degrees-C. Almost all the copolymers degrade in one step. The kinetic parameters E(a), n and A were obtained following one method of thermogravimetric analysis. The thermal stability depends on the copolymer composition which was determined from the H-1 NMR spectra. The most stable material was poly(p-nitrophenylmaleimide-co-2-methylaziridine).
dc.fuente.origenWOS
dc.identifier.issn0040-6031
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/99055
dc.identifier.wosidWOS:A1991GJ54000017
dc.issue.numero1
dc.language.isoen
dc.pagina.final172
dc.pagina.inicio163
dc.revistaThermochimica acta
dc.rightsacceso restringido
dc.titleTHERMAL-DEGRADATION AND DETERMINATION OF KINETIC-PARAMETERS BY DYNAMIC THERMOGRAVIMETRY OF COPOLYMERS SYNTHESIZED WITHOUT INITIATOR
dc.typeartículo
dc.volumen188
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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