Modification of ferroelectric hysteresis in Pb(Nb,Zr,Ti)O<sub>3</sub> thin films induced by CO<sub>2</sub> adsorption

dc.contributor.authorRamos-Moore, E.
dc.contributor.authorLederman, D.
dc.contributor.authorCabrera, A. L.
dc.date.accessioned2025-01-21T00:00:08Z
dc.date.available2025-01-21T00:00:08Z
dc.date.issued2011
dc.description.abstractWe report on the modification of ferroelectric hysteresis in Pb(Nb,Zr,Ti)O-3 thin films under the adsorption of CO2 gas. The samples were exposed to the gas in ultra high vacuum while different voltages between the top (Ag) and bottom (Pt) electrodes were applied. After dosing, the samples were heated from room temperature at 1.8 K/s, and a mass spectrometer was used to detect the desorbed molecules. The effective molecular sticking was demonstrated by the appearance of the carbon Auger peak in the surface of the sample and by the presence of CO2 in the desorption curves. After +(-) 9.9 V were applied to the bottom electrode during dosing, we found a shift of 0.52 (+0.58) mu C/cm(2) in the remnant polarization. These evidences suggest the existence of a depolarizing field induced by molecular adsorption at the surface of the top electrode, and contribute to highlight the potential use of ferroelectric thin films as gas sensors. (C) 2011 Elsevier B.V. All rights reserved.
dc.fuente.origenWOS
dc.identifier.doi10.1016/j.apsusc.2011.09.067
dc.identifier.issn0169-4332
dc.identifier.urihttps://doi.org/10.1016/j.apsusc.2011.09.067
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/95326
dc.identifier.wosidWOS:000296725000032
dc.issue.numero3
dc.language.isoen
dc.pagina.final1183
dc.pagina.inicio1181
dc.revistaApplied surface science
dc.rightsacceso restringido
dc.subjectFerroelectric thin films
dc.subjectCarbon dioxide adsorption
dc.subjectPb(Nb,Zr,Ti)O-3
dc.subjectGas sensing
dc.subject.ods07 Affordable and Clean Energy
dc.subject.odspa07 Energía asequible y no contaminante
dc.titleModification of ferroelectric hysteresis in Pb(Nb,Zr,Ti)O<sub>3</sub> thin films induced by CO<sub>2</sub> adsorption
dc.typeartículo
dc.volumen258
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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