The Diels-Alder reaction of 1-cyclohexenecarbaldehyde N,N-dimethylhydrazone with juglone
dc.contributor.author | Valderrama, JA | |
dc.contributor.author | Spate, M | |
dc.contributor.author | Gonzalez, MF | |
dc.date.accessioned | 2025-01-21T01:33:38Z | |
dc.date.available | 2025-01-21T01:33:38Z | |
dc.date.issued | 1997 | |
dc.description.abstract | The synthesis of 1-cyclohexenecarbaldehyde N,N-dimethylhydrazone 7 from cyclohexanecarbaldehyde by using a three step sequence is reported. The Diels-Alder reaction of juglone 5 with azadiene 7 provides hexahydrobenzo[b]phenantridine 14a in 55% tetrahydrobenzo[b]phenantridines 15a and 15b. Angular tetracyclic quinone 15a was formed in 47% yield by caning out the cycloaddition of 5 and 7 in the presence of oxygen. Under this oxidant condition compound 15a undergoes partial oxidation to tetracyclic quinone 17. | |
dc.fuente.origen | WOS | |
dc.identifier.issn | 0793-0283 | |
dc.identifier.uri | https://repositorio.uc.cl/handle/11534/97450 | |
dc.identifier.wosid | WOS:A1997WL26100003 | |
dc.issue.numero | 1 | |
dc.language.iso | en | |
dc.pagina.final | 28 | |
dc.pagina.inicio | 23 | |
dc.revista | Heterocyclic communications | |
dc.rights | acceso restringido | |
dc.subject.ods | 03 Good Health and Well-being | |
dc.subject.odspa | 03 Salud y bienestar | |
dc.title | The Diels-Alder reaction of 1-cyclohexenecarbaldehyde N,N-dimethylhydrazone with juglone | |
dc.type | artículo | |
dc.volumen | 3 | |
sipa.index | WOS | |
sipa.trazabilidad | WOS;2025-01-12 |