Quantitative characterization of the global electrophilicity power of common diene/dienophile pairs in Diels-Alder reactions

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dc.contributor.authorDomingo, LR
dc.contributor.authorAurell, MJ
dc.contributor.authorPérez, P
dc.contributor.authorContreras, R
dc.date.accessioned2025-01-21T01:30:25Z
dc.date.available2025-01-21T01:30:25Z
dc.date.issued2002
dc.description.abstractThe global electrophilicity power, omega, of a series of dienes and dienophiles commonly used in Diels-Alder reactions may be conveniently classified within a unique relative scale. Useful information about the polarity of transition state structures expected for a given reaction may be obtained from the difference in the global electrophilicity power, Deltaomega. of the diene/dienophile interacting pair. Thus the polarity of the process can be related with non-polar (Deltaomega small, pericyclic processes) and polar (Deltaomega big, ionic processes) mechanisms. (C) 2002 Elsevier Science Ltd. All rights reserved.
dc.fuente.origenWOS
dc.identifier.eissn1464-5416
dc.identifier.issn0040-4020
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/96748
dc.identifier.wosidWOS:000175892400008
dc.issue.numero22
dc.language.isoen
dc.pagina.final4423
dc.pagina.inicio4417
dc.revistaTetrahedron
dc.rightsacceso restringido
dc.subjectDiels-Alder reactions
dc.subjectelectrophilicity power
dc.subjectdensity functional theory
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa03 Salud y bienestar
dc.titleQuantitative characterization of the global electrophilicity power of common diene/dienophile pairs in Diels-Alder reactions
dc.typeartículo
dc.volumen58
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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