Photocatalytic study of TiO2 thin films modified with Anderson-type polyoxometalates (Cr, Co and Ni): Experimental and DFT study

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dc.contributor.authorDiaz-Uribe, Carlos
dc.contributor.authorDuran, Freider
dc.contributor.authorVallejo, William
dc.contributor.authorPuello, Esneyder
dc.contributor.authorZarate, Ximena
dc.contributor.authorSchott, Eduardo
dc.date.accessioned2025-01-20T20:18:58Z
dc.date.available2025-01-20T20:18:58Z
dc.date.issued2023
dc.description.abstractIn this work, three Anderson-type polyoxomolybdates (POMs) with general formula (NH4)6-n[XMo6O24H6]- 6+n where X = Co3+, Cr3+, and Ni2+ were deposited on TiO2 thin films Furthermore, the methylene blue (MB) dye adsorption capacity and photocatalytic degradation were studied. Morphological results show that the POMs/TiO2 films have a more heterogeneous surface in terms of particle size and distribution than bare TiO2 films. Optical characterization indicated that the CrMo6/TiO2 material had the lowest band gap energy with a value of 2.8 eV. The adsorption results show that the maximum percentage of MB adsorption was 37 % for NiMo6/TiO2 while bare TiO2 has only 9.2 %. The MB adsorption on POMs-TiO2 was modeled using and the Freundlich model showed the best fit in all studied films for MB removal. The MB photodegradation values shows this tendency 12 % for bare TiO2, 55 % for NiMo6/TiO2, 73 % for NiMo6/TiO2 and, 83 % for CrMo6/ TiO2. Finally, DFT calculations were performed to characterize the geometry and electronic structure of the all compounds studied in this work, with the aim to explain the observed experimental results.
dc.fuente.origenWOS
dc.identifier.doi10.1016/j.poly.2022.116253
dc.identifier.eissn1873-3719
dc.identifier.issn0277-5387
dc.identifier.urihttps://doi.org/10.1016/j.poly.2022.116253
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/92495
dc.identifier.wosidWOS:000916166400001
dc.language.isoen
dc.revistaPolyhedron
dc.rightsacceso restringido
dc.titlePhotocatalytic study of TiO2 thin films modified with Anderson-type polyoxometalates (Cr, Co and Ni): Experimental and DFT study
dc.typeartículo
dc.volumen231
sipa.indexWOS
sipa.trazabilidadWOS;2025-01-12
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