Browsing by Author "Campos, P"
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- ItemChelating properties of the anionic iridium(III) complex [(eta(5)-C(5)Me(5))IrCl{PO(OMe)(2)}(2)](-). Synthesis of bi- and trinuclear derivatives(1996) Valderrama, M; Campos, PThe synthesis and properties of new neutral complexes of the type [(eta(5)S-C(5)Me(5))IrX{PO(OMe)(2)} {P(OH)(OMe)(2)}] (X=Cl, I) and their thallium derivatives. [(eta(5)-C(5)Me(5))IrX{PO(OMe)(2)}Tl-2] are described. The potentially bidentate or terdentate ligand being the anionic complex [(eta(5)-C(5)Me(5)) IrCl{PO(OMe)(2)}(2)](-) has been studied. It reacts with metal ions and with some organometallic fragments to yield trinuclear or binuclear complexes Spectroscopy data for the isolated complexes are discussed.