Statistics for Chiral sulfur diphosphazanes derived from S-(Ph<sub>2</sub>P)<sub>2</sub>N(CHMePh) and its rhodium(I), (III) and iridium(III) complexes. Crystal structures of Ph<sub>2</sub>P(S)N(CHMePh)PPh<sub>2</sub>, {Ph<sub>2</sub>P(S)}<sub>2</sub>N(CHMePh) and [(Cp*)MCl{η<SUP>2</SUP>-P,S-Ph<sub>2</sub>PNHP(S)Ph<sub>2</sub>}]BF<sub>4</sub>, Cp* = η<SUP>5</SUP>-C<sub>5</sub>Me<sub>5</sub>; M = Rh, Ir

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Chiral sulfur diphosphazanes derived from S-(Ph<sub>2</sub>P)<sub>2</sub>N(CHMePh) and its rhodium(I), (III) and iridium(III) complexes. Crystal structures of Ph<sub>2</sub>P(S)N(CHMePh)PPh<sub>2</sub>, {Ph<sub>2</sub>P(S)}<sub>2</sub>N(CHMePh) and [(Cp*)MCl{η<SUP>2</SUP>-P,S-Ph<sub>2</sub>PNHP(S)Ph<sub>2</sub>}]BF<sub>4</sub>, Cp* = η<SUP>5</SUP>-C<sub>5</sub>Me<sub>5</sub>; M = Rh, Ir 0

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