Browsing by Author "Villarroel, Mirza"

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    CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEED
    (2017) Bassi, Romina; Camu, Esteban; Villarroel, Mirza; Gil-Llambias, Fco. Javier; Garcia-Fierro, J. L.; Escalona, Nestor; Baeza, Patricio
    The effect of supports and the addition of CS2 in the feed were studied on hydrodenitrogenation of Quinoline in a continuous flow reactor over ReS2/support catalysts at 300, 325 and 350 degrees C and 3MPa of H-2. The ReS2 supported on TiO2 displayed the highest activity followed by ZrO2, gamma-Al2O3 and SiO2 supports. The activity trend was correlated with the Re dispersion on the support. The effect of the addition of CS2 was increased activity until 2.5 v/v % content. At higher CS2 content the activity decreased due to competitive adsorption between CS2 and Quinoline on the active sites.