Browsing by Author "VILDOSOLA, G"

Now showing 1 - 1 of 1
  • No Thumbnail Available
    Item
    MONOALKYLITACONATES VINYLPYRROLIDONE COPOLYMERS .2. REACTIVITY RATIOS AND VISCOMETRIC BEHAVIOR IN DILUTE-SOLUTIONS
    (1993) RADIC, D; OPAZO, A; VILDOSOLA, G; GARGALLO, L
    Copolymerization of mono-n-octyl, mono-n-decyl and mono-n-dodecyl itaconate with vinylpyrrolidone (MOI-VP, MDI-VP and MDoI-VP) was carried out using AIBN as initiator. The monomer reactivity ratios were determined by the Fineman-Ross and Kelen-Tudos methods. Values of r1 and r2 were found to be less than unity for MOI-VP, MDI-VP and MDoI-VP, corresponding to random copolymers with some tendency to alternance. Copolymers of various compositions were studied in solution, and Mark-Houwink-Kuhn-Sakurada relationships were established in ethanol for MOI-VP and MDI-VP copolymers, and in 1-propanol for MDoI-VP. The rigidity factors sigma and the characteristic ratio C(infinity) were obtained from K(theta) values determined by using the Stockmayer-Fixman relation. In all the copolymers the introduction of vinylpyrrolidone units produces flexibility of the polymer chain relative to the poly(monoitaconate) homopolymers, and the solution properties of these copolymers can be described by assuming a random coil model instead of a rigid rod or wormlike model as in poly(monoitaconates).