Browsing by Author "Saltarini, Sebastián"
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- ItemToward a Neutral Single-Component Amidinate Iodide Aluminum Catalyst for the CO2 Fixation into Cyclic Carbonates(2021) Saltarini, Sebastián; Villegas, Nery Andrés; Martínez, Javier; Daniliuc, Constantin G.; Matute, Ricardo A.; Gade, Lutz H.; Rojas Guerrero, René
- ItemTrapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex(2021) Villegas-Escobar, Nery ; Martínez, Javier ; Matute, Ricardo A. ; Saltarini, Sebastián ; Daniliuc, Constantin G. ; Gade, Lutz H. ; René S. RojasA neutral trialuminum complex incorporates a pentacoordinate carbon through a methylidene bridge linking the three metal atoms. The rigid electron-deficient Al-3 core stabilizes the hypercoordinate carbon atom resulting in the shortest equatorial Al-C distance reported for such an Al-3-(mu(3)-CH2) unit.