Browsing by Author "Osorio Roman, Igor"

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    CdTe quantum dots modified electrodes ITO-(Polycation/QDs) for carbon dioxide reduction to methanol
    (ELSEVIER, 2020) Guzman, Diego; Isaacs, Mauricio; Tsukuda, Tatsuya; Yamazoe, Seiji; Takahata, Ryo; Schrebler, Ricardo; Burgos, Ana; Osorio Roman, Igor; Castillo, Francisco
    The present work describes the characterization by atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and electrochemical techniques of ITO modified electrodes with electrostatic assemblies (Polycation/Quantum Dots) and their use in the electro- and photoelectrocatalytic reduction of CO2. These assemblies were prepared with polycations poly-diallyldimethylammonium (PD) and poly-(2-trimethylammonium) ethyl methacrylate (PM) and nanocrystals of CdTe of 2.77 nm (Q2). The size of the nanocrystals was controlled by the synthesis reflux time and incorporated by electric field directed Layer-by-Layer assembly method (EFDLA). The polycations were characterised by NMR measurements; showing important effects on the electrostatic assemblies. PM modified electrodes, with its lower rigidity, exhibited less roughness than the PD modified electrodes, 8.0 nm versus 32.8 nm, and higher heterogeneity in its surface composition. Higher resistance to the charge transfer and time constants were obtained with PMQ2 modified electrode, 63.8 Omega cm(-2) and 2.69 ms versus 49.30 Omega cm(-2) and 1.3 ms for PDQ2. The electro- and photoelectro properties for CO 2 reduction were studied through j-E curves and potential controlled electrolysis. Modified surfaces were active toward the reduction of CO2, with a positive shift of the activity between darkness and irradiation conditions, 0.050 V with PDQ2 and 0.450 V with PMQ2. The main product of the CO2 reduction was CH3OH, with traces of CO and HCOOH. The PM modified electrodes with QDs of 2.77 nm presented a selective behaviour for the production of CH3OH.
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    Multimetallic porphyrins/polyoxotungstate modified electrodes by layer-by-layer method: Electrochemical, spectroscopic and morphological characterization
    (PERGAMON-ELSEVIER SCIENCE LTD, 2012) Garcia, Macarena; Carfuman, Karla; Diaz, Carlos; Garrido, Carlos; Osorio Roman, Igor; Jesus Aguirre, M.; Isaacs, Mauricio
    This work describes the formation of modified electrodes layer-by-layer assembly of a mu-{meso-5,10,15,20-tetra(pyridyl)porphyrin}terrakis{bis(bipyridine)chloride ruthenium(II)} coordinated with Zn(II) and Mn(III) in its central cavity and an anionic polyoxotungstate [SiW12O40](4-). The bilayer formation was monitored using electrochemical and UV-vis techniques, following the oxidation process of the Ru-III/II couple and the absorbance of the Soret band of porphyrin complexes respectively. It was possible to form 10 stable bilayers onto ITO surface. SEM studies were carried out finding that the morphology of the film depends on the metal center in the porphyrin. The thickness of these films was estimated as 0.603 mu m for (Zn(II)TRP](4+)/[SiW12O40](4-) and 2.18 mu m for [Mn(III)TRP](5+)/[[SiW12O40](4-) modified electrodes respectively. Raman spectroscopy showed that new bands appeared for [Mn(III)TRP](5+)/[SIW12O40](4-) assembly confirming stronger interactions than only electrostatic forces.