Browsing by Author "Maureira-Carsalade, Nelson"

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    Analyzing Influence of Mix Design Constituents on Compressive Strength, Setting Times, and Workability of Geopolymer Mortar and Paste
    (2023) Oyejobi, Damilola; Jameel, Mohammed; Adewuyi, Adekunle; Aina, Samuel; Avudaiappan, Siva; Maureira-Carsalade, Nelson
    Geopolymer concrete and mortar have evolved over the years as potential alternatives for reducing the greenhouse gases associated with cement production. This current research was aimed at investigating the optimum dosage and concentration of sodium hydroxide required to leach out silica and alumina oxides in the fly ash for geopolymerization to take place. Blackish grey fly ash from Morupule, Botswana, was synthesized by varying sodium hydroxide (NaOH) of 98% purity between 8 M and 14 M, respectively. The ratio influence of sodium hydroxide to fly ash in dissolving the oxides was carried out at the values of 0.55, 0.62, and 0.75. The results showed that the workability of the geopolymer mortar and paste decreased with the increase in the ratio of fly ash to alkaline activator. The highest workability was achieved at a ratio of 0.75 : 1. The compressive strength, setting time, and workability of geopolymer mortar and paste can be controlled by adjusting the ratio of fly ash to alkaline activator. A ratio of 1.5 : 1 was found to be the most suitable for achieving high compressive strength, while a ratio of 0.75 : 1 was found to be the most suitable for achieving high workability. Furthermore, the workability values were in the range of 105 to 143 mm, while the ranges of initial and final setting times were found to be between 280-350 and 950-1170 minutes, respectively. This study is significant because no previous study has carried out geopolmerization of the Morupule fly ash as a result of its unique characteristics. These findings have important implications for the development of sustainable construction materials. The main finding was that for optimum reaction to take place, and NaOH/fly ash ratio should be kept at 0.55 and molarity of 12 to avoid leaching of other oxides that might weaken the strength.
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    Characterisation of Sodium Acetate Treatment on Acacia pennata Natural Fibres
    (2023) Sheeba, Kasirajan Rajam Jaya; Priya, Retnam Krishna; Arunachalam, Krishna Prakash; Avudaiappan, Siva; Maureira-Carsalade, Nelson; Roco-Videla, Angel
    The present study concerns the physico-chemical, structural, mechanical and thermal characterization of Acacia pennata, a natural and almost inexpensive fibre, as a potential reinforcement in polymer composites. The effect of treating the fibre with sodium acetate to increase its qualities has been seen through the use of thermogravimetric analysis, scanning electron microscope (SEM) analysis, X-ray diffraction (XRD), mechanical property tester, and Fourier transform infrared spectroscopy (FTIR). According to XRD analysis, the elimination of lignin and wax-like impurities resulted in an increase in the AP fibre's crystalline index (79.73%). The fibre's thermal stability was also discovered to be 365 degrees C. Tensile strength (557.58 MPa) and elongation at break both increased by 2.9% after treatment with sodium acetate. The surface nature and quality of AP fibres improved after sodium acetate treatment. It was confirmed by the reduction of chemical compositions (such as hemicellulose, lignin and pectin). Given its density, the fibre can be suggested as a reinforcement in polymer composites for light-weight applications because its lightweight property will be more useful for composite manufacturing.
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    Innovative Use of Single-Use Face Mask Fibers for the Production of a Sustainable Cement Mortar
    (2023) Avudaiappan, Siva; Cendoya, Patricio; Arunachalam, Krishna Prakash; Maureira-Carsalade, Nelson; Canales, Cristian; Amran, Mugahed; Parra, Pablo F.
    Due to the COVID-19 epidemic, biomedical waste management has overwhelmed both developed and developing nations. It is now a critical issue that has to be addressed with minimal possible adverse impact on the environment. This study introduced a technique of recycling face masks into polypropylene fibers for use in concrete. This proposed recycling process provides complete disinfection of contaminated clinical waste and offers the opportunity to transform the characteristics of an end product. Microfibers manufactured from recycled medical masks were subjected to testing. According to the results, polypropylene is the primary component of this research program. Two batches of concrete were made, one with the inclusion of masks as polypropylene fibers and another that performed as a control mix. The modified mortar was compared to the control mix in split tensile, flexure, compressive strength, and water absorption. Compressive strength was found to be improved by about 17%, and tensile strength to be increased by around 22% when mask fibers were incorporated. This research introduced a novel approach for disposing of waste masks and established the preliminary viability of upcycling trash face masks towards mortar concrete production.
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    Investigating the Mechanical, Thermal, and Crystalline Properties of Raw and Potassium Hydroxide Treated Butea Parviflora Fibers for Green Polymer Composites
    (2023) Mohan, Abisha; Priya, Retnam Krishna; Arunachalam, Krishna Prakash; Avudaiappan, Siva; Maureira-Carsalade, Nelson; Roco-Videla, Angel
    The only biotic factor that can satisfy the needs of human species are plants. In order to minimize plastic usage and spread an immediate require of environmental awareness, the globe urges for the development of green composite materials. Natural fibers show good renewability and sustainability and are hence utilized as reinforcements in polymer matrix composites. The present work concerns on the usage of Butea parviflora fiber (BP), a green material, for high end applications. The study throws light upon the characterization of raw and potassium hydroxide (KOH)-treated Butea Parviflora plant, where its physical, structural, morphological, mechanical, and thermal properties are analyzed using the powder XRD, FTIR spectroscopy, FESEM micrographs, tensile testing, Tg-DTA, Thermal conductivity, Chemical composition, and CHNS analysis. The density values of untreated and KOH-treated fibers are 1.238 g/cc and 1.340 g/cc, respectively. The crystallinity index of the treated fiber has significantly increased from 83.63% to 86.03%. The cellulose content of the treated fiber also experienced a substantial increase from 58.50% to 60.72%. Treated fibers exhibited a reduction in both hemicelluloses and wax content. Spectroscopic studies registered varying vibrations of functional groups residing on the fibers. SEM images distinguished specific changes on the raw and treated fiber surfaces. The Availability of elements Carbon, Nitrogen, and Hydrogen were analyzed using the CHNS studies. The tensile strength and modulus of treated fibers has risen to 192.97 MPa and 3.46 Gpa, respectively. Thermal conductivity (K) using Lee's disc showed a decrement in the K values of alkalized BP. The activation energy Ea lies between 55.95 and 73.15 kJ/mol. The fibers can withstand a good temperature of up to 240 & DEG;C, presenting that it can be tuned in for making sustainable composites.
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    Investigation on Properties of Raw and Alkali Treated Novel Cellulosic Root Fibres of Zea Mays for Polymeric Composites
    (2023) Kavitha, S. Anne; Priya, R. Krishna; Arunachalam, Krishna Prakash; Avudaiappan, Siva; Maureira-Carsalade, Nelson; Roco-Videla, Angel
    Today, new materials based on natural fibres have been emerging day by day to completely eradicate plastics to favour our environmental nature. In this view, the present work is based on the extraction and characterisation of the novel root fibres of the Zea mays (Zm) plant, grown by the hydroponic method. Both the dried untreated and alkali treated root fibres are investigated using a variety of structural, morphological, thermal, elemental and mechanical tests by subjecting both the samples to p-XRD, FT-IR, SEM-EDAX, TGA-DTA, CHNS and tensile strength analyses. Thermal conductivity of the untreated and treated fibres is found using Lee's disc experiment. From p-XRD analysis, the Crystallinity Index, Percentage Crystallinity and Crystallite size of the samples are found. FT-IR studies clarify the different vibrational groups associated with the fibre samples. SEM images show that the surface roughness increases for the chemically treated samples, such that it may be effectively utilised as reinforcement for polymeric composites. The diameter of the fibre samples is found using SEM analysis. According to the EDAX spectrum, Zm fibres in both their raw and processed forms have high levels of Carbon (C) and Oxygen (O). The TGA-DTA tests revealed that the samples of natural fibre have good thermal characteristics. CHNS studies show that Carbon content is high for these samples, which is the characteristic of many natural fibres. Chemical analysis is used to ascertain the prepared samples' chemical makeup. It reveals that both samples have significant amounts of cellulose. The density of the fibres is found to be in the range 0.3-0.6 g/cc, which is much less than any other natural fibre. Therefore, it can be used in light weight applications. From the tensile strength analysis, physical properties such as Young's modulus and micro-fibril angle are determined. The fibres in the roots exhibit a lower tensile strength. Thus, these fibres can be used in powdered form as reinforcement for natural rubber or epoxy composites. After examining all of its properties, it could be reasonably speculated that Zea mays root fibres can be considered as an efficient reinforcement for various matrices to produce attractive bio-composites.
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    Non-Destructive Assessment of the Elastic Properties of Low-Grade CLT Panels
    (2021) Opazo-Vega, Alexander; Benedetti, Franco; Nunez-Decap, Mario; Maureira-Carsalade, Nelson; Oyarzo-Vera, Claudio
    The use of cross-laminated timber panels (CLT) made of low-grade structural timber has steadily increased in developing countries. These panels usually present several natural defects, which can cause a high local variation of their orthotropic elastic properties, generating future structural serviceability problems. Our work aims to estimate the local variability of the elastic properties in low-grade CLT panels by combining nondestructive transverse vibration testing, numerical simulations, and regional sensitivity analysis (RSA). Four three-layer Radiata pine CLT panels were subjected to transverse vibration tests with supports at four points. Besides, a series of numerical simulations of the panels, considering the local variability of the elastic properties of the panels in eight zones, were carried out using the finite element method. Then, RSA analysis was performed to study in which ranges of values the panels' elastic properties generated lower differences between the measured versus simulated dynamic properties. Finally, a structural quality control indicator was proposed for the CLT panels based on keeping low the probability that the elastic properties in the central zones do not exceed minimum acceptable values. The results obtained suggest that the proposed methodology is suitable for segregating CLT panels with high concentrations of defects such as pith presence.