Browsing by Author "Colet-Lagrille, Melanie"

Now showing 1 - 1 of 1
  • No Thumbnail Available
    Item
    Effects of Ti3C2Tx nano-sheets (MXenes) on the microstructural and electrochemical properties of SnO2/Ti anodes
    (2021) Gonzalez-Poggini, Sergio; Rosenkranz, Andreas; Wang, Bo; Hevia, Samuel; Yu, Jinhong; Colet-Lagrille, Melanie
    The effects of the incorporation of Ti3C2Tx nano-sheets (MXenes) on the microstructure of SnO2/Ti electrodes and their electro-oxidation catalytic activity for the degradation of methyl red is studied in this work. MXenes-SnO2/Ti electrodes are fabricated by spin-coating followed by a thermal treatment under ambient atmospheric conditions using a solution containing MXene nano-sheets, SnCl2, citric acid and ethylene glycol as precursor. Energy-dispersive X-ray spectroscopy, Raman spectroscopy and Xray diffraction analyses of the MXenes-SnO2/Ti electrodes surface indicate the formation of SnO2-TiO2 films with Ti4+ ions incorporated into the lattice of SnO2 crystals. Cyclic voltammetry curves demonstrate that the oxygen evolution reaction is restrained by the MXenes-SnO2/Ti electrodes, while the methyl red electro-oxidation is enhanced - with kinetics following a pseudo-first-order model compared to the performance of (pure) SnO2/Ti electrodes. These results suggest that oxygen vacancies are formed in the crystal lattice of MXenes-SnO2/Ti electrodes, which act as charge carriers and increase the electrical conductivity of SnO2 as confirmed by the lower charge transfer resistance of MXenes-SnO2/Ti electrodes determined by electrochemical impedance spectroscopy analysis.