Browsing by Author "Castro Quijada, Matías Daniel"

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    A Study on Copper Mine Tailings to Be Used as Precursor of Alkali-Activated Materials for Construction Applications
    (2025) Morales Castro, Luis Felipe; Loyola Fernández, Estefanía Francisca; Castro Quijada, Matías Daniel; Vargas, Felipe; Navarrete Leschot, Iván Ignacio; Eugenin Soto, Claudia Andrea; Marquardt Román, Carlos Jorge; Videla Leiva, Álvaro Rodrigo
    This research presents a novel methodology to classify copper tailings according to their potential as alkali-activated materials (AAMs) for construction applications. The methodology includes geochemical and mineralogical characterization via QEMSCAN and X-ray fluorescence, with mechanical performance evaluation through compressive strength test (UCS). A three-phase diagram based on Al2O3, Fe2O3, and CaO-MgO-K2O is proposed for a fast screening of copper tailing potential to be used as a construction material. In this paper, three copper tailings were chosen to test the methodology, and a set of five samples for each tailing have been geopolymerized for testing. Copper tailing samples were mixed with 0, 2.5, 5, 7.5 and 10% by mass of Ordinary Portland Cement (OPC) to evaluate the effect on performance when a chemical co-activator is used to improve material reactivity. Compressive strength testing was applied on 2 cm3 cubes after 28 days of curing at 60 °C, yielding values from 6 to 26.1 MPa. The best performing sample featured a Si/Al ≅ 3 ratio and a mineralogy with significant presence of reactive species such as plagioclase and K-feldspar (≅42%). In contrast, high levels of Fe2O3 (≥12%), clay (≥7%), and pyrite (≥4%) were associated with reduced mechanical performance.
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    Assessing the performance of novel molten salt mixtures on CSP applications
    (2024) Starke, Allan R.; Cardemil Iglesias, José Miguel; Bonini, Vinicius R.B.; Escobar Moragas, Rodrigo; Castro Quijada, Matías Daniel; Videla Leiva, Álvaro Rodrigo
    The use of molten salt mixtures as a storage medium in Concentrating Solar Power (CSP) plants has been shown to have a significant impact on increasing the reliability of CSP plants and reducing the levelized cost of energy. In this context, the present work presents the implementation of a detailed simulation procedure that contemplates different design considerations for the Rankine cycle to maximize its efficiency according to the temperature constraints established by utilizing different molten salt mixtures. To achieve this, three commercial CSP plant configurations were considered: an indirect coupling using parabolic trough collectors (PTC) with thermal oil as field heat transfer fluid (HTF) and molten salts as the storage medium, a direct coupling of PTC using molten salt as HTF and storage medium, and a central receiver plant (solar tower). The analysis considers the integration strategy between the solar system and the thermal storage, where all of those configurations considered the integration of the two-tank (hot/cold) approach. The analysis enables the development of an accurate estimation of the economic performance of changing the HTF in CSP plants, as well as the assessment of the parasitic consumption due to freezing protection systems, the effect of increasing the current field temperature, and the effect on the plant’s capacity factor. The results show that the improvement in conversion efficiencies associated with salt mixtures operating at higher temperatures induces a higher electricity generation; however, such improvement is not compensated by the material change costs within the specified considerations.